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93.
Báez AP Torres Mdel C García RM Padilla HG 《Environmental science and pollution research international》2002,9(4):230-233
A great number of studies on the ambient levels of formaldehyde and other carbonyls in the urban rural and maritime atmospheres have been published because of their chemical and toxicological characteristics, and adverse health effects. Due to their toxicological effects, it was considered necessary to measure these compounds at different sites in the metropolitan area of Mexico City, and to calculate the total rate of photolytic constants and the photolytic lifetime of formaldehyde and acetaldehyde. Four sites were chosen. Sampling was carried out at different seasons and atmospheric conditions. The results indicated that formaldehyde was the most abundant carbonyl, followed by acetone and acetaldehyde. Data sets obtained from the 4 sites were chosen to calculate the total rate of photolysis and the photolytic lifetime for formaldehyde and acetaldehyde. Maximum photolytic rate values were obtained at the maximum actinic fluxes, as was to be expected. 相似文献
94.
P. Steven Porter Robert C. Ward 《Journal of the American Water Resources Association》1991,27(4):687-700
ABSTRACT: The statistical analysis of data which have trace level measurements has traditionally been a two-step process in which data are first censored using criteria based on measurement precision, and then analyzed with statistical methods for censored data. The process might be more informative if data were left uncensored. In this paper, information loss attributable to censoring and measurement noise are assessed by comparing the sample mean and median of uncensored measurements with a log regression mean and median based on censored data. Measurements are derived from lognormal parent distributions which have random variability characteristic of trace level measurement. The relative performance of estimators used with error-free samples and with samples having measurement noise can be explained by differences between the probability distributions of parents and measurements. Measurement introduces bias and dispersion and transforms lognormal parent distributions toward greater symmetry. Estimates using uncensored data are less biased and more accurate than the log regression mean and median when censoring exceeds about 50 percent, and are not much worse at any fraction censored. For data with many (80 percent) results below the limit of detection, bias may be quite severe. 相似文献
95.
Lee H. MacDonald 《Journal of the American Water Resources Association》1993,29(3):357-368
ABSTRACT: Recent assessments have emphasized the lack of a field and laboratory component in hydrologic education at the university level. Consequences of this lack include: (1) an unwarranted faith in published data; (2) lack of appreciation for the spatial and temporal variability of most hydrologic processes; (3) lack of appreciation for the difficulty of collecting good quality field data; (4) an inability to design and execute projects to collect field data; (5) a lack of field experience which can be applied when confronted with different problems or new environments; (6) an inability to evaluate published materials or models against “field reality;” (7) an excessive reliance on, and trust in, theoretical or conceptual models; and (8) reduced potential for lifelong learning through observation and analysis. Field courses need not be costly or difficult, but the instructor must be willing to adapt to the uncertainty and problems associated with field measurements. A recently updated course on watershed measurements at Colorado State University illustrates the type of field courses which can be developed if there is the necessary commitment and flexibility. The lack of a current text can be overcome by assembling selected portions of existing government documents, and a sample bibliography is included. 相似文献
96.
A. A. M. Langenhoff J. J. M. Staps C. Pijls A. Alphenaar G. Zwiep H. H. M. Rijnaarts 《Water, Air, & Soil Pollution: Focus》2002,2(3):171-181
The feasibility of the biodegradation of HCH and its intermediates has been investigated. A recent characterisation of two sites in The Netherlands has shown intrinsic biodegradation of HCH. At one site, breakdown products (monochlorobenzene, benzene and chlorophenol) were found in the core of the HCH-plume, whereas the HCH-concentration decreased over time and space. Characterisation of a second, industrial site indicated less intrinsic biodegradation and the need to stimulate biodegradation. In the laboratory, enhanced HCH degradation was tested with soil and groundwater material from both sites, and the required conversion to the intermediates benzene and monochlorobenzene was demonstrated. Furthermore, the biodegradation of these intermediates could be initiated by adding low amounts of oxygen (<5%). Adding nitrate enhanced this degradation. We hypothesise that this occurs through anaerobic nitrate reducing conversion of oxidised intermediates.At the non-industrial other site, intrinsic degradation took place, as shown in the laboratory experiments. Interpretation of the field data with computer codes Modflow and RT3D was performed. As a result of the modelling study, it has been proposed to monitor natural attenuation for several years before designing the final approach.At the industrial site, the results of the batch experiments are applied. Anaerobic HCH degradation to monochlorobenzene and benzene is stimulated via the addition of an electron donor.Infiltration facilities have been installed at the site to create an anaerobic infiltration zone in which HCH will be degraded, and these facilities are combined with the redevelopment of the site. 相似文献
97.
David O. Cook James W. Demenkow Priya J. Wickramaratne John T. Hannigan 《Journal of the American Water Resources Association》1978,14(2):440-453
ABSTRACT: The town of Jamestown, Rhode Island, located on Conanicut Island in Narragansett Bay, is constructing a secondary treatment plant in order to comply with NPDES regulations. Twelve candidate sites for the plant and marine outfall were initially proposed, and ability to meet State water quality standards at these sites was evaluated using an EPA buoyant plume model. A final outfall site, Taylor Point, was selected by the Town from among the sites considered acceptable. Taylor Point was then subjected to field hydrographic studies including drogue tracking, current recordings, and tracer dye surveys. Results of the measurement program served as input to a two-dimensional effluent dispersion model which predicted excess BOD, coliform, and suspended solids resulting from effluent discharge off Taylor Point. The model predictions demonstrated that State water quality standards can be maintained outside the initial discharge plume. 相似文献
98.
B. Houston Atwell R. B. MacDonald Luis A. Bartolucci 《Journal of the American Water Resources Association》1971,7(2):228-243
This paper begins with a brief review of radiation theory as applied to water temperature determinations. Errors introduced in “radiant” temperature measurements due to nonblackness of the water surface and the effects of the atmosphere are included in this discussion. The airborne scanner system is described. Analysis and display of scanner data using the Laboratory for Applications of Remote Sensing (LARS) display system are discussed. Thermal maps of four sections of the Wabash River are included and points of interest of each map are discussed in the text. 相似文献
99.
REN Nan-qi YAN Xian-feng CHEN Zhao-bo HU Dong-xue GONG Man-li GUO Wan-qian 《环境科学学报(英文版)》2007,19(2):129-134
The lack and pollution of water resource make wastewater reuse necessary. The pilot scale long-term tests for submerged membrane bioreactor were conducted to treat the effluents of anaerobic or aerobic treatment process for the high-strength Chinese traditional medicine wastewater. This article was focused on the feasibility of the wastewater treatment and reuse at shorter hydraulic retention time (HRT) of 5.0, 3.2 and 2.13 h. MLSS growth, membrane flux, vacuum values and chemical cleaning periods were also investigated. The experimental results of treating two-phase anaerobic treatment effluent demonstrated that the CODfilt was less than 100 mg/L when the influent COD was between 500-10000 mg/L at HRT of 5.0 h, which could satisfy the normal discharged standard in China. The experimental results to treat cross flow aerobic reactor effluent demonstrated that the average value of CODfilt was 17.28 mg/L when the average value of influent COD was 192.84 mg/L at HRT of 2.13 h during 106 d, which could completely meet the normal standard for water reuse. The maximum MLSS and MLVSS reached 24000 and 14500 mg/L at HRT of 3.2 h respectively. Membrane flux had maximal resume degrees of 94.7% at vacuum value of 0.02 MPa after cleaning. Chemical cleaning periods of membrane module were 150 d. A simulation model of operational parameters was also established based on the theory of back propagation neural network and linear regression of traditional mathematical model. The simulation model showed that the optimum operational parameters were suggested as follows: HRT was 5.0 h, SRT was 100 d, the range of COD loading rate was between 10.664-20.451 kg/(m3.d), the range of MLSS was between 7543-13694 mg/L. 相似文献
100.
通过使用德国TriOS公司生产的RAMSES-ACC-UV/VIS光谱仪,在2016—2017年对西藏四个地区(拉萨、林芝、阿里和定日)进行了阶段性的太阳光谱(波长280—950 nm)实地观测。初步研究了西藏四个地区地面太阳光谱强度、光谱曲线特征以及光谱随时间的变化等,结果显示在本次观测期间,2017年7月21日(晴天)当地正午(北京时间13点58分)拉萨晴天光谱在476.6 nm波长处出现强度最高,峰值达到2.05 W?m~(-2)?nm~(-1)。同时对比了观测期间拉萨与定日、拉萨与林芝的当地正午晴天太阳光谱特征,对比结果表明:定日光谱强度高于拉萨,拉萨光谱强度高于林芝。定日光谱曲线平滑程度高于拉萨,拉萨光谱曲线平滑程度高于林芝,主要由水汽、氧气吸收造成。 相似文献